Structure of Atom

1. Introduction

  • What is an atom?
  • Historical development of atomic theories.

2. Subatomic Particles

  • Electron:
    • Discovered by J.J. Thomson (Cathode ray experiment).
    • Charge and mass of an electron.
  • Proton:
    • Discovered by Goldstein (Canal ray experiment).
    • Properties of protons.
  • Neutron:
    • Discovered by James Chadwick.
    • Properties of neutrons.

3. Atomic Models

  • Thomson’s Model:
    • Plum pudding model.
    • Limitations.
  • Rutherford’s Model:
    • Gold foil experiment.
    • Observations and conclusions.
    • Limitations.
  • Bohr’s Model:
    • Postulates.
    • Energy levels and quantization.
    • Successes and limitations.

4. Quantum Mechanical Model

  • Introduction to quantum theory.
  • Dual nature of matter and light:
    • Wave nature: Electromagnetic spectrum.
    • Particle nature: Planck’s quantum theory.
  • De Broglie’s hypothesis.
  • Heisenberg’s uncertainty principle.
  • Schrödinger wave equation and orbitals.

5. Atomic Structure

  • Atomic Number (Z): Number of protons in the nucleus.
  • Mass Number (A): Total number of protons and neutrons.
  • Isotopes, isobars, and isotones.
  • Representation: ZAX_{Z}^{A}\text{X}ZA​X.

6. Electronic Configuration

  • Aufbau principle.
  • Pauli’s exclusion principle.
  • Hund’s rule of maximum multiplicity.
  • Distribution of electrons in shells (s, p, d, f).

7. Applications of Atomic Models

  • Use in spectroscopy
  • Importance in astrophysics
  • Nuclear energy applications

8. Key Formulas and Derivations

  • Bohr radius formula: rn=n2h24π2me2r_n = \frac{n^2h^2}{4\pi^2me^2}rn​=4π2me2n2h2​
  • Energy of electron in nth orbit: En=−13.6n2E_n = -\frac{13.6}{n^2}En​=−n213.6​ eV
  • Rydberg formula: 1λ=R(1n12−1n22)\frac{1}{\lambda} = R \left(\frac{1}{n_1^2} – \frac{1}{n_2^2}\right)λ1​=R(n12​1​−n22​1​)

9. Summary and Revision Tips

  • Key differences between atomic models
  • Focus on Bohr’s derivations and hydrogen spectrum
  • Practice numerical problems related to energy and radii

10. Practice Questions

  • MCQs: Conceptual and application-based
  • Numerical problems: Calculate orbit radii, energy, wavelength of spectra
  • Short-answer and long-answer questions

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